From the classic Outer Limits episode "The Zanti Misfits" (Leonard Horn, 1963); One of the titular convicts from another planet seems unconcerned that a large can of Raid is about to be employed off camera by star Bruce Dern.

Said alien being an early example of work by the great stop-motion animator Jim Danforth, by the way.

I should add that whenever I hear people in New York City complaining about the recent vermin infestations, I whip out this photo and then tell 'em to STFU.